By Alois Fuerstner
Content material: Olefin metathesis by way of well-defined complexes of molybdenum and tungsten / R.R.Schrock -- Ruthenium-catalyzed metathesis reactions in natural synthesis / A. Furstner -- Ring-closing metathesis within the synthesis of epothilones and polyether average items / K.C. Nicolaou, N.P. King, Y. He -- Catalytic ring-closing metathesis and the advance of enantioselective procedures / A.H. Hoveyda -- Enyne metathesis / M. Mori -- Cross-metathesis / Susan E. Gibson, S.P. willing -- fresh advances in ADMET chemistry / D. Tindall, J.H. Pawlow and K.B. Wagener -- Bioactive polymers / L.L. Kiessling, L.E. powerful
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Additional resources for Alkene Metathesis in Organic Synthesis
Schrock RR (1995) Polyhedron 14:3177 8. Schwab P, France MB, Ziller JW, Grubbs RH (1995) Angew Chem Int Ed Engl 34:2039 9. Schwab P, Grubbs RH, Ziller JW (1996) J Am Chem Soc 118:100 10. Grubbs RH, Miller SJ, Fu GC (1995) Acc Chem Res 28:446 11. Demonceau A, Stumpf AW, Saive E, Noels AF (1997) Macromolecules 30:3127 12. Thorn-Csányi E, Dehmel J, Luginsland HD, Zilles JU (1997) J Mol Catal A 115:29 13. Clark JS, Kettle JG (1997) Tet Lett 38:123 14. Fox HH, Schrock RR (1994) Organometallics 13:635 15.
5 Effects of Oleﬁn Substitution . . . . . Functional Group Compatibility . . . . Ring Size . . . . . . . . . . . Sequential Transformations . . . . . . Metathesis Reactions in Solid Phase Synthesis . . . 46 51 51 58 59 4 Oleﬁn Metathesis in Supercritical Carbon Dioxide . . . . . 59 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 A. Fürstner 5 Selected Applications of RCM to Target Oriented Synthesis . . . 6 Carbocyclic Nucleosides .
A. the allenylidene complexes 2), as well as recent advancements related to the use of supercritical carbon dioxide (scCO2) as reaction medium for RCM, will be discussed. Keywords: Ruthenium-carbenes, Ruthenium-allenylidenes, Ring closing metathesis, Natural product synthesis, Fine chemicals. 1 Introduction . . . . . . . . . . . . . . . . 38 2 Synthesis, Structure, Mechanism and Activity of Ruthenium-Based Metathesis Catalysts . . . . . . . . 3 Ruthenium Carbene Complexes and General Aspects of RCM .