Download Applied optics and optical engineering. Vol. I: Light. Its by R. Kingslake PDF

By R. Kingslake

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2, and (b) the Nernst relation [eq. 3»). 22 The most important part of the theory for the discharge behavior of Li-insertion batteries concerns the transport of Li+ -ions through the electrolyte and in the solid insertion electrode. Ouring the discharge process, the ion concentration in the electrolyte increases at the anode and decreases at the cathode surface. The concentration changes in the electrolyte and the surface of the insertion compound cooperate to create a negative overvoltage, which depresses the discharge voltage of the battery.

_.......... _... __.. _--- ---'... - ... 29. LVS curves of Bi2SJ during the first discharge-charge cycle at room temperature. 2. 1. Performance of thin-film cells There are several parameters which specify the size-dependent properties of solid electrolyte electrochemical systems. Among these we may mention the size of the electrolyte itself, the size of the cathode, and the size of the active cathode particles if the cathode is prepared in the form of a dispersed electrode. One of advantage of solid electrolyte systems is that in a planar geometry the perpendicular dimension may be decreased to potentially very small dimensions.

Experimental EPS set-up Here, we discuss only the experimental system and the evaluation of kinetic parameters. V to the galvanic cell. The activity of lithium, and thus the concentration in the cathodic material at the electrode-electrolyte interface, is abruptly changed from the concentration Co to a new constant value C s. Reequilibration of the composition within the cathode to the value C s by chemical diffusion involves transport across the electrolyte-electrode interface, and thus current through the cell.

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