Download Makromolekule, Band 2: Physikalische Strukturen und by Prof. Dr. Hans?Georg Elias(auth.) PDF

By Prof. Dr. Hans?Georg Elias(auth.)

Content:
Chapter 1 Einleitung (pages 1–3):
Chapter 2 Chemische Struktur (pages 4–39):
Chapter three Mikrokonformationen (pages 40–65):
Chapter four Makrokonformationen (pages 66–137):
Chapter five Streumethoden (pages 138–169):
Chapter 6 Ungeordnete kondensierte Systeme (pages 170–184):
Chapter 7 Kristalline Zustande (pages 185–234):
Chapter eight Mesophasen (pages 235–267):
Chapter nine Polymere in und an Grenzflachen (pages 268–291):
Chapter 10 Thermodynamik von Polymerlosungen (pages 292–362):
Chapter eleven shipping in Losungen (pages 363–394):
Chapter 12 Viskositat verdunnter Losungen (pages 395–425):
Chapter thirteen Thermische Eigenschaften (pages 426–469):
Chapter 14 delivery in Polymeren (pages 470–490):
Chapter 15 Viskositat von Schmelzen (pages 491–516):
Chapter sixteen Elastizitat (pages 517–567):
Chapter 17 Viskoelastizitat (pages 568–610):
Chapter 18 Bruch von Polymeren (pages 611–633):

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Extra info for Makromolekule, Band 2: Physikalische Strukturen und Eigenschaften, Sechste Auflage

Sample text

Statische und dynamische Glastemperaturen ...................... Andere Umwandlungen und Relaxationen ........................ 6. 2. 3. 4. 14. Transport in Polymeren .......................................................................... 1. Einleitung ........................................................................................ 2. Transport in fluiden Polymerphasen ................................................ 1. Losungsmittel in konzentrierten Polymerlbsungen ............ 2. Polymere in Schmelzen .....................................................

Zum Beispiel zwei beim Poly(ethy1en-co-propylen) und bis zu zwanzig bei unmodifizierten Proteinketten: R#H2-CH24H2-. -- N H - - C H , - - C ~ H R~H,-CH,-CH,~H-CH,-CH,-. ~ H~ - ~C ~H CH, Poly(g1ycin) - - c ein ~ Protein H C,H* Der Suuktur nach unterscheidet man femer zwischen Kettengliedem. Monomereinheiten, konstitutionellen Repetiereinheiten und Segmenten einerseits und Endgruppen andererseits (E: end groups). Wenn man auf die Monomereinheiten abstellt (E: monomer(ic) units), sind H und OH die beiden Endgruppen des Poly(glycins).

Aufstellen. Sueng genommen gelten alle diese Beziehungen und die Folgenden nur f i r ringfdrmige bzw. unendlich lange Ketten, bei denen die Endeinheiten vemachllssigbar sind. ). Die Stoffmengenanteile an isotaktischen Diaden, Triaden, Tetraden usw. sind bei isotaktischen Polymeren jeweils Eins (xi = xii = xi;; = ... = 1). Bei syndiotaktischen Polymeren gilt entsprechend x, = x,, = x,,, = ... = 1. Da heterotaktische Polymere aus jeweils gleichen Anteilen an iso- und syndiotaktischen Diaden bestehen, hat man hier xi = x, = lr;!

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